(《拾遗》)
【释名】白 (音腊)、 (音引)、贺。
时珍曰∶《尔雅》∶锡,谓之 。郭璞注云∶白 也。方术家谓之贺,盖锡以临贺出者为
美也。
【集解】《别录》曰∶锡,生桂阳山谷。
弘景曰∶今出临贺,犹是桂阳地界。铅与锡相似,而入用大异。
时珍曰∶锡出云南、衡州。许慎《说文》云∶锡者,银铅之间也。《土宿本草》云∶锡
受太阴之气而生,二百年不动成砒,砒二百年而锡始生。锡禀阴气,故其质柔。二百年不动,
遇太阳之气乃成银。今人置酒于新锡器内,浸渍日久或杀人者,以砒能化锡,岁月尚近,便
被采取,其中蕴毒故也。又曰∶砒乃锡根。银色而铅质,五金之中独锡易制,失其药则为五
金之贼,得其药则为五金之媒。《星槎胜览》言∶满刺加国,于山溪中淘沙取锡,不假煎炼
成块,名曰斗锡也。
【正误】恭曰∶临贺采者名铅,一名白 ,惟此一处资天下用。其锡,出银处皆有之。
体相似,而入用大异。
时珍曰∶苏恭不识铅、锡,以锡为铅,以铅为锡。其谓黄丹、胡粉为炒锡,皆由其不识
故也。
今正之。
【气味】甘,寒,微毒。独孤滔曰∶ 羊角、五灵脂、伏龙肝、马鞭草皆能缩贺。 、
砒能硬锡。巴豆、蓖麻、姜汁、地黄能制锡。松脂焊锡。锡矿缩银。
【主治】恶毒风疮(大明)。
【发明】时珍曰∶洪迈《夷坚志》云∶汝人多病瘿。地饶风沙,沙入井中,饮其水则生
瘿。故金房间人家,以锡为井阑,皆夹锡钱镇之,或沉锡井中,乃免此患。
【附方】新二。
解砒霜毒∶锡器,于粗石上磨水服之。(《济急方》)
杨梅毒疮∶黑铅、广锡各二钱半(结砂),蜈蚣二条,为末,纸卷作小捻,油浸一夜,
点
灯日照疮二次,七日见效。(《集玄方》)
(From *Bencao Shiyi* [Supplement to Materia Medica])
[Names] Baixi (White Tin, pronounced "La"), Yinyin (Lead Tin, pronounced "Yin"), He.
Li Shizhen states: *Erya* records that tin is called Baixi. Guo Pu's annotation says it is white tin. Alchemists call it He, likely because tin from Linhe is considered the finest.
[Collection and Explanation] *Mingyi Bielu* [Record of Famous Physicians] states: Tin is produced in the valleys of Guiyang.
Tao Hongjing says: It is now produced in Linhe, which still belongs to the jurisdiction of Guiyang. Lead and tin look similar, but their medicinal uses are vastly different.
Li Shizhen says: Tin is produced in Yunnan and Hengzhou. Xu Shen in *Shuowen Jiezi* [Explanations of Simple Graphs and Analysis of Compound Characters] states: Tin is a metal between silver and lead. *Tusux Bencao* [Materia Medica of Tu Su] states: Tin is born receiving the Qi of Great Yin; if left undisturbed for two hundred years, it turns into arsenic; after another two hundred years, arsenic generates tin again. Tin inherits Yin Qi, therefore its texture is soft. If left undisturbed for two hundred years and exposed to the Qi of Great Yang, it transforms into silver. Nowadays, people place wine in new tin vessels; if soaked for a long time, it may cause death. This is because arsenic can transform tin. Since the time elapsed is relatively short, it is mined, and thus contains hidden toxicity. It is also said that arsenic is the root of tin. Tin is silver-colored but has the quality of lead. Among the Five Metals [Gold, Silver, Copper, Iron, Tin], only tin is easy to smelt. Without proper medicinal regulation, it becomes a thief among the metals; with proper regulation, it becomes a medium for the metals. *Xingcha Shenglan* [Victorious Navigation] states: In the country of Malacca, tin is extracted by washing sand in mountain streams without the need for smelting, forming blocks known as Douxi.
[Correction of Errors] Su Gong says: The material mined in Linhe is named lead, also called Baixi, and this single source supplies the entire world. True tin is found wherever silver is produced. Their physical forms are similar, but their medicinal applications are vastly different.
Li Shizhen says: Su Gong did not distinguish between lead and tin, mistaking tin for lead and lead for tin. His claim that Huangdan [Red Lead] and Hufen [Cerussa] are made from fried tin stems entirely from his lack of knowledge.
This is now corrected.
[Flavor and Properties] Sweet, cold, slightly toxic. Dugu Tao says: Sheep horn, Wulingzhi [Trogopterus Dung], Fulonggan [Pillared Earth], and Mabianncao [Verbena officinalis] can all cause He tin to contract. He tin and arsenic can harden tin. Badou [Croton Seed], Bimazu [Castor Bean], Jiangzhi [Ginger Juice], and Dihuang [Rehmannia Root] can control tin. Songzhi [Pine Resin] is used to solder tin. Tin ore can shrink silver.
[Indications] Toxic wind sores (from *Daming Bencao*).
[Elucidation] Li Shizhen says: Hong Mai's *Yijian Zhi* [Records of Hearing and Seeing] states: People in Ruzhou often suffer from goiter. The land is rich in wind and sand; sand enters the wells, and drinking this water causes goiter. Therefore, households in Jinfang use tin for well rims, suppressing them with coins containing tin, or sinking tin into the well to avoid this affliction.
[Attached Prescriptions] Two new prescriptions.
To resolve Arsenic Poisoning: Use a tin vessel, grind it on a coarse stone to obtain tin water, and drink it. (*Jiji Fang* [Urgent Emergency Formulas])
For Chancre (Syphilis): Black lead and Guangxi tin, each 2.5 qian (processed into powder), two centipedes, ground into powder, rolled into small paper twists, soaked in oil overnight, then applied to the sore twice under lamp light. Visible effects appear within seven days. (*Jixuan Fang*)